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精萘的主要分类及相关特点
来源:http://www.jnjdbc.cn/ 日期:2023-02-28 发布人:admin
焦油萘
Tar naphthalene
从煤焦油中提取的萘称作焦油萘。在高温煤焦油中萘约占8-12%。从焦油精馏塔侧线切取下温度区段为210-230℃的萘油馏分,历经清洗脱酚,再精馏分离出来轻组分,便可获得凝固点为78℃、纯度为96%的工业萘。
Naphthalene extracted from coal tar is called tar naphthalene. In high-temperature coal tar, naphthalene accounts for about 8-12%. The naphthalene oil fraction with a temperature range of 210-230 ℃ is cut from the side line of the tar distillation tower. After cleaning and dephenolization, the light components are separated by distillation, and then the industrial naphthalene with a freezing point of 78 ℃ and purity of 96% can be obtained.
工业萘中含残渣硫茚(1-3%)、甲基萘(1-2%)及小量茚、焦油碱和焦油酸,历经进步酸洗钝化和水蒸气蒸馏,可获得硫含量低于0.1%、凝固点为79℃的精萘。若必须进步特制使硫含量小于0.05%,则需选用加氢精制加工工艺。
Industrial naphthalene contains residues of indene (1-3%), methyl naphthalene (1-2%), and small amounts of indene, tar base and tar acid. After advanced acid pickling and passivation and steam distillation, refined naphthalene with sulfur content less than 0.1% and freezing point of 79 ℃ can be obtained. If the sulfur content must be improved to be less than 0.05%, the hydrofining process should be selected.
石油萘
Petroleum naphthalene
石油萘的原料来源于于催化重整、催化裂化和氮化合物裂化等全过程的重芳烃组分。在催化重整油中,甲基萘的含水量约为55%。先历经提纯和吸咐,从原料馏分中分离出来出萘的各种各样同系物,随后选用催化反应临氢脱烷基的方式,以Cr2O3-Al2O3为金属催化剂,在400-800℃和0.5-7兆帕下开展临氢脱甲基反映,反映物质经制冷液相化学物质后,水蒸气蒸馏去除轻组分苯、二甲苯、二甲苯等,终进步精馏可获得石油萘商品。商品用有机溶剂消化吸收和有机溶剂清洗的方式开展纯化,纯度达到99.73%。
The raw material of petroleum naphthalene comes from the heavy aromatic components in the whole process of catalytic reforming, catalytic cracking and nitrogen compound cracking. In the catalytic reforming oil, the water content of methylnaphthalene is about 55%. After purification and adsorption, various homologues of naphthalene were separated from the raw material fraction, and then the hydrodealkylation reaction was carried out using Cr2O3-Al2O3 as a metal catalyst, at 400-800 ℃ and 0.5-7 MPa. After the reaction material was cooled by liquid-phase chemical substances, the light components of benzene, xylene, xylene, etc. were removed by steam distillation, and finally the petroleum naphthalene products could be obtained by progressive distillation. The commodity is purified by organic solvent digestion and absorption and organic solvent cleaning, and the purity reaches 99.73%.
据统计,以轻柴油为裂化原料的年产量30万吨级的丁二烯设备,,可副产焦油9万吨级,在其中萘和萘潜量为4-5万吨级。
According to statistics, the butadiene equipment with an annual output of 300000 tons using light diesel oil as the cracking feedstock can produce 90000 tons of tar by side, of which the naphthalene and naphthalene potential are 40000 to 50000 tons.
主要用途
Main purpose
工业生产精萘是基本化工厂原料,适用于生产制造外加剂、外扩散剂,是生产制造树脂材料、阻燃剂、橡胶防老剂,表活剂,人造纤维,染剂、药业和香辛料等的原料。
Refined naphthalene for industrial production is the raw material of basic chemical plants, which is suitable for the production and manufacture of additives and external dispersants. It is also the raw material for the production and manufacture of resin materials, flame retardants, rubber antioxidants, surfactants, man-made fibers, dyes, pharmaceuticals and spices.
本文由精萘厂家提供技术支持,更多的详细精彩内容请点击我们的网站http://www.jnjdbc.cn我们将会全心全意为您提供满意的服务。
This article is supported by the refined naphthalene manufacturer. For more details, please click our website http://www.jnjdbc.cn We will wholeheartedly provide you with satisfactory service.
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